The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Cracking results both from the stresses induced by the internal pressure due to the recombination of hydrogen on specific sites in the microstructure, and from the hydrogen embrittling effect, weakening the cohesive forces within the metal. For hydrogen induced cracking to take place, individual hydrogen atoms must cluster at the surface of the metal to create hydrogen molecules. Hic in welding cold cracking haz cracking moisture n org compounds r primary sources of h. The nace specification defines the scc as the cracking of metal involving corrosion and stress both residual and or applied in the presence of h2s and water. In the presence of water and hydrogen sulfide, atomic hydrogen is produced.
In the case of hydrogeninduced corrosion cracking occurs see also corrosion cracking with stress corrosion cracking. Dear muthukrishnan, i would exclude also hydrogen attack as root cause of the crack formation. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. A metallographic analysis of these steels was performed before and after nace tm0284 standard testing. Carbon and low alloy steels which are subjected to sour service environments may be susceptible to hydrogen induced cracking hic. Hydrogen induced cracking hic in the oil and gas industry. In susceptible alloys, the hydrogen combines with carbon within the alloy and forms methane.
Corrosion products were characterized by scanning electron microscopy and xray dispersive energy spectrometry, which were. Hydrogen induced cracking of hard materials zthe refining industry has had very few cases of hydrogen related cracking in pure hydrogen service. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Mechanisms of hydrogen induced cracking in pipeline steels in iom3. Hydrogeninduced cracking also referred to as cold cracking, is caused by the diffusion of hydrogen in the crystal lattice of haz near the fusion boundary atomic hydrogen is dispersed throughout the weld material, making it weak in mechanical properties. Hydrogen induced cracking in carbon steel in sour service is a common damage mechanism. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. Hydrogen induced cracking hic remains a prominent issue for oil and. Hydrogen induced blister cracking and mechanical failure in. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys.
H2s partial pressures and the lowest ph values aqueous medium acidities. This pressure can increase to levels where the metal has reduced ductility, toughness, and tensile strength, up to the point where it cracks open hydrogeninduced cracking, or hic. However, the test environment of nace tm028496 standard hic test method is unnecessarily severe than that of actual sour service conditions. The equilibrium pressure of the molecular hydrogen in the void, which is in contact with the atomic hydrogen in the surrounding metal, is great enough to rupture any metal or alloy. Hydrogen induced cracks either follow a linear or stepwise path within the material, hence the term stepwise cracking. Hydrogeninduced cracking hic is still a challenging issue that requires careful. According to iso 15156, hydrogeninduced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen.
Hydrogen embrittlement of pipelines and remediation mixing with water. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Hydrogen embrittlement is mainly a problem in steels with ultimate tensile strength greater than 90 ksi, although a number of additional alloys are susceptible. The method is based on standard hic tests and hydrogen permeation experiments, which are correlated to yield a threshold hydrogen concentration below which no cracks will be initiated. At high temperature and high hydrogen partial pressure, hydrogen can diffuse into carbon steel alloys. The pressure of the hydrogen gas causes localized internal cracks, known as. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. The diffusion coefficient for the hydrogen atom in the spv50q steel was determined at 2560 c and the activation energy for diffusion was 24.
Stress corrosion cracking scc and sulfide stress cracking ssc are the most. A comparative study of hydrogeninduced cracking resistances. An electron backscatter diffraction ebsd micrograph of hic induced by laboratory testing of an x52 alloy is shown in fig. The problems can be minimised through the circulation of corrosion inhibiting chemicals or the selection of corrosion resistant alloys. The hydrogen induced cracking hic resistance of several grades of plate steels was. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. European studies on the effect of water composition and ph resulted in these. From my point of view chlorides from test water cannot be excluded as cause for cl induced scc if the final hydrotest of the vessels has not been performed with demineralized water in case of designs which are not gap free or at least flushed with demineralized water after hydrotest if the design is.
Gas phase water needs to be there as well even in a trace amount. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang dept. The methane molecules create a pressure buildup in the metal lattice voids, which leads to embrittlement and even cracking of the metal. Over time, the metal becomes so brittle that it cracks. Susceptibility to hydrogen induced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. Effect of partial pressure of hydrogen on igscc of alloy 600. May 19, 2009 hic is prevalent in wet h 2 s environments, which is often known as sour service and such cracking over a prolonged period of time without inspection, will reach a critical point and the steel component i. Under these operating conditions the predominant failure mechanism is hydrogen cracking, of which there are several types. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Cosasco provides hydrogen monitoring solutions for corrosion control such as hydrogen blistering hydrogen induced cracking hic on steel. The blistering damage tends to form parallel to the surface and to the direction of hoop stress.
The pressure of the hydrogen gas causes localized internal cracks, known as hydrogen induced cracks. Hydrogeninduced cracking an overview sciencedirect topics. Effects of temperature and pressure on stress corrosion. Material and metallurgical parameters were investigated. Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. The diffusion of atomic hydrogen into the material in combination with tensile stress results in embrittlement and cracking. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Detection of hydrogen induced cracks during inservice.
Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. May 07, 2019 sulfide stress corrosion cracking occurs in presence of hydrogen sulfide. Abstract as a first step, a literature survey was undertaken on hydrogen induced cracking hic phenomena. According to iso 15156, hydrogen induced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. The presence of hydrogen atoms in a metal degrades some of its mechanical properties, especially its ductility, leading in some cases to embrittlement. However, under certain stress and material conditions, the cracks can be arranged in a ladderlike array known as stress. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Material selection for sour service environment pipeline. In the presence of water and hydrogen sulfide, atomic hydrogen is produced and enters the steel, recombining at discontinuities to form molecular gases hydrogen gases. Roles of microalloying elements in hydrogen induced.
Critical hydrogen partial pressure in hydrogen embrittlement. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased. Plates of high strength, low alloy hsla steel jisg3115 spv50q were found to be susceptible to sulfide stress cracking and hydrogeninduced cracking hic in wet hsub 2s. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies. Simulated tests have been carried out in simulated solution containing high concentration of chloride, with high hydrogen sulphide partial pressure, at high stress level and at 120 c for 720 hours. Sep 07, 2009 the methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Hydrogen induced cracking steel features, applications. Crack faces are exposed to a hydrogen gas pressure and hydrogen. Acid gas corrosion research at curtin curtin corrosion centre houses state of the art research facilities that can simulate complex operating conditions. Types of corrosion materials selection guide swagelok.
Plates of high strength, low alloy hsla steel jisg3115 spv50q were found to be susceptible to sulfide stress cracking and hydrogen induced cracking hic in wet hsub 2s. This process is known as hydrogen embrittlement or hydrogeninduced cracking. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Detection, characterization and sizing of hydrogen induced. Corrosionpedia what is hydrogeninduced cracking hic. Effect of hydrogen partial pressure on the hydrogen.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Element offers hydrogen induced corrosion hic tests to accurately assess the. The literature sources suggested a variety of methodologies that can be used for ffp. From my point of view chlorides from test water cannot be excluded as cause for cl induced scc if the final hydrotest of the vessels has not been performed with demineralized water in case of designs which are not gap free or at least flushed with demineralized water after hydrotest if the. Hydrogen induced cracking hic remains a prominent issue for oil and gas exploration in.
The entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength. Roles of microalloying elements in hydrogen induced cracking. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stressoriented hydrogen induced cracking sohic. Additionally, hydrogen atoms diffuse through metals and coalesce. It is often assumed that hic is just a subcategory of sulfide stress cracking. Hydrogen cracking its causes, costs and future occurrence. Abstract h 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. Sour gas cracking or sulfide stress cracking at high hydrogen sulfide h 2 s partial pressure sour gas cracking, also known as sulfide stress cracking ssc, is the deterioration of metal due to contact with hydrogen sulfide h 2 s and moisture. It is a type of hydrogen induced cracking hic in which the primary poison is the evolution of atomic hydrogen. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials.
Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. Weld metal hydrogen cracking in pipeline girth welds, proc. Sandia national laboratories is a multi program laboratory managed and operated by sandia corporation, a wholly owned subsidiary of lockheed martin corporation, for the u. Corrosion generally involves carbon dioxide co2, sweet corrosion, or hydrogen sulphide h2s, sour corrosion. In both cases, water must be present for corrosion to occur. As the concentration levels of hydrogen sulphide increase, sour operating conditions start to prevail i. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Hydrogen embrittlement, also called hydrogen stress cracking or hydrogen induced cracking, is a condition of low ductility in metals resulting from the absorption of hydrogen. Sulfide stress cracking an overview sciencedirect topics. Sulfide stress corrosion cracking occurs in presence of hydrogen sulfide. Specifying valves for hydrogen service valve magazine.
Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. In the case of hydrogen induced corrosion cracking occurs see also corrosion cracking with stress corrosion cracking. Hydrogen cracking is also named as toe cracking or underbead cracking due to its location of occurrence. Hydrogeninduced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms. Thus hydrogen induced blistering can be seen as a special case of the plane pressure mechanism of hydrogen embrittlement, where high pressure hydrogen forms in. Particularly common to the oil and gas industry where the use of steel. Environmental cracking susceptibility of low alloy steel. The hydrogen deleterious effect has a relevant industrial and economic impact being, at the same time, a challenge from the scientific point of view. Hydrogen induced blister cracking and mechanical failure. In the gas phase, a stream is sour if the h2s partial pressure exceeds 0. This clustering produces pressure in the metal which results in the metal losing ductility, toughness and tensile strength. A comparative study of hydrogeninduced cracking resistances of. Ferritic stainless steels, on the other hand, tend to be fairly resistant to hydrogen stress cracking due to their comparatively low hardness.
Aug 02, 2014 the entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength. The frequently reported effect of the partial pressure of hydrogen on the alloy 600 susceptibility to intergranular stress corrosion cracking igscc in hightemperature water is explained in this paper. Environmental cracking susceptibility of low alloy steel octg. In ssrts in 5%h 2ar gas, which is the fundamental environment, the relative reduction of area was 1.
Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Adsorbed hydrogen species recombine to form hydrogen molecules, creating pressure from within the metal. Equivalently, low temperature hydrogen induced cracking was also noticed in inconel 718. Cathodic overpotential and hydrogen partial pressure. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. The diffusible hydrogen content in the deposited metal significantly increased from 23. Simply put, hydrogen induced cracking damage increases as the level of hydrogen sulphide increases. Hydrogen induced cracking hic on steel for corrosion. Effect of partial pressure of hydrogen on igscc of alloy. Stress corrosion cracking behavior of nickel base alloys. Stress corrosion crackingscc is the main corrosion failure mode for 310s stainless steel.
Processes or conditions involving wet hydrogen sulfide, i. H 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. A method has been developed for determination of the maximum allowed aggressiveness of sour media in pipelines of which the steel has a given susceptibility to hydrogeninduced cracking hic. Hydrogen induced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Hydrogen induced cracking steel features, applications and. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms.